全文获取类型
收费全文 | 92095篇 |
免费 | 13860篇 |
国内免费 | 9181篇 |
专业分类
化学 | 62619篇 |
晶体学 | 964篇 |
力学 | 5998篇 |
综合类 | 641篇 |
数学 | 11615篇 |
物理学 | 33299篇 |
出版年
2024年 | 70篇 |
2023年 | 1771篇 |
2022年 | 1898篇 |
2021年 | 2727篇 |
2020年 | 3406篇 |
2019年 | 3317篇 |
2018年 | 2882篇 |
2017年 | 2586篇 |
2016年 | 3986篇 |
2015年 | 3992篇 |
2014年 | 4786篇 |
2013年 | 6458篇 |
2012年 | 8050篇 |
2011年 | 8409篇 |
2010年 | 5687篇 |
2009年 | 5554篇 |
2008年 | 5887篇 |
2007年 | 5360篇 |
2006年 | 4957篇 |
2005年 | 4256篇 |
2004年 | 3349篇 |
2003年 | 2563篇 |
2002年 | 2350篇 |
2001年 | 2008篇 |
2000年 | 1837篇 |
1999年 | 2005篇 |
1998年 | 1680篇 |
1997年 | 1523篇 |
1996年 | 1603篇 |
1995年 | 1412篇 |
1994年 | 1307篇 |
1993年 | 1111篇 |
1992年 | 1009篇 |
1991年 | 859篇 |
1990年 | 721篇 |
1989年 | 621篇 |
1988年 | 459篇 |
1987年 | 444篇 |
1986年 | 379篇 |
1985年 | 382篇 |
1984年 | 248篇 |
1983年 | 219篇 |
1982年 | 178篇 |
1981年 | 132篇 |
1980年 | 93篇 |
1978年 | 64篇 |
1977年 | 57篇 |
1976年 | 60篇 |
1975年 | 69篇 |
1973年 | 61篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Theoretical study of (e,2e) triple differential cross sections of pyrimidine and tetrahydrofurfuryl alcohol molecules using multi-center distorted-wave method 下载免费PDF全文
We report theoretical studies of electron impact triple differential cross sections of two bio-molecules,pyrimidine and tetrahydrofurfuryl alcohol,in the coplanar asymmetric kinematic conditions with the impact energy of 250 eV and ejected electron energy of 20 eV at three scattering angles of-5°,-10°,and-15°.Present multi-center distorted-wave method well describes the experimental data,which was obtained by performing(e,2e)experiment.The calculations show that the secondary electron produced by the primary impact electron is strongly influenced by the molecular ionic multi-center potential,which must be considered when the low energy electron interacts with DNA analogues. 相似文献
42.
Unified convergence analysis of a second-order method of multipliers for nonlinear conic programming
Science China Mathematics - In this paper, we accomplish the unified convergence analysis of a second-order method of multipliers (i.e., a second-order augmented Lagrangian method) for solving the... 相似文献
43.
Restricted testing conditions were considered recently. For the maximal operator, Hytönen, Li and Sawyer [8] first obtained parental testing condition. Later, they [9] showed that it suffices to restrict testing to doubling cubes. Chen and Lacey [3] gave a similar restricted testing condition. In our paper, we discuss a version of the latter in the multilinear setting.
相似文献44.
HUA Cong WANG Xuanzhong LIANG Shipeng LI Chen CHEN Xi PIAO Meihua WANG Zhenchuan GE Pengfei LUO Tianfei 《高等学校化学研究》2022,38(4):1089-1096
Ferroptosis triggered by hemin is regarded as a primary factor accounting for neuronal death secondary to intracerebral hemorrhage. Thus, compounds with inhibitory effect on hemin-induced ferroptosis might be potential medicines to prevent neuronal death caused by intracerebral hemorrhage. Herein, we investigate whether maltol could alleviate hemin-induced SH-SY5Y cell ferroptosis and its potential mechanisms. It is found that maltol effectively prevents hemin-induced SH-SY5Y cell ferroptosis via three pathways. The first one is inhibiting intracellular iron increase via preventing upregulation of transferrin receptor, the second one is alleviating lipid peroxidation via attenuating H2O2 generation by NOX4 and promoting H2O2 clearance by catalase, and the third one is to reduce peroxidized lipids via maintaining GPX4/GSH pathway. Therefore, maltol is a novel agent preventing hemin-induced SH-SY5Y cell ferroptosis. 相似文献
45.
Chen Fenge Li Bing Peng Xingchun 《Methodology and Computing in Applied Probability》2022,24(2):635-659
Methodology and Computing in Applied Probability - This paper is devoted to the study of an optimal investment and risk control problem for an insurer. The risky asset process and the insurance... 相似文献
46.
Yi-Tong Xu Tian-Yang Zhang Zheng Li Xiang-Nan Liu Yuan-Cheng Zhu Wei-Wei Zhao Hong-Yuan Chen Jing-Juan Xu 《Electroanalysis》2022,34(6):947-955
Photoelectrochemical (PEC) cytosensors, a combination of the PEC process and the living-cell assay, have emerged as a powerful tool in the analytical and biological science. This mini review provides a brief introduction of this arena and summaries the key steps about the development of PEC cytosensors with representative examples, followed by future prospects based on our own opinions. 相似文献
47.
Mathematical Notes - Let $$\mathbb N$$ denote the set of all nonnegative integers, and let $$A\subseteq\mathbb N$$ . Let $$h,n\in\mathbb N$$ , $$h\ge 2$$ and $$r_h(A,n)=\#\{(a_1,\dots,a_h)\in... 相似文献
48.
Asymmetric mode transformation in waveguide is of great significance for on-chip integrated devices with one-way effect, while it is challenging to achieve asymmetric nonlinear-mode-conversion (NMC) due to the limitations imposed by phase-matching. In this work, we theoretically proposed a new scheme for realizing asymmetric NMC by combining frequency-doubling process and periodic PT symmetric modulation in an optical waveguide. By engineering the one-way momentum from PT symmetric modulation, we have demonstrated the unidirectional conversion from pump to second harmonic with desired guided modes. Our findings offer new opportunities for manipulating nonlinear optical fields with PT symmetry, which could further boost more exploration on on-chip nonlinear devices assisted by non-Hermitian optics. 相似文献
49.
Bohuai Xiao Jianqiao Dong Zhiye Wang Xu Wang Mingjun Sun Jing Guo Gongming Qian Yunchuan Li Shuai Chang 《Chemphyschem》2022,23(7):e202100833
One important prerequisite for the fabrication of molecular functional device strongly relies on the understanding the conducting behaviors of the metal-molecule-metal junction that can respond to an external stimulus. The model Lewis basic molecule 4,4′-(pyridine-3,5-diyl)dibenzonitrile (DBP), which can react with Lewis acid and protic acid, was synthesized. Then, the molecular conducting behavior of DBP, DBP-B(C6F5)3, and DBP-TfOH (DBP-B(C6F5)3, and DBP-TfOH were produced by Lewis acid and protonic acid treatment of DBP) was researched and compared. Given that their identical physical paths for DBP, DBP-B(C6F5)3, and DBP-TfOH to sustain charge transport, our results indicate that modifying the molecular electronic structure, even not directly changing the conductive physical backbone, can tune the charge transporting ability by nearly one order of magnitude. Furthermore, the addition of another Lewis base triethylamine (of stronger alkaline than DBP), to Lewis acid-base pair reverts the electrical properties back to that of a single DBP junction, that is constructive to propose a useful but simple strategy for the design and construction of reversible and controllable molecular device based on pyridine derived molecule. 相似文献
50.
Heterostructured MoS2/GPC anode: the synergistic lithium storage performance and lithiation kinetics
Zhang Xia Dong Chaoyang Sun Yangang Liu Binyang Sun Lili Lu Yongjuan Yu Jing Wei Yajun Xu Yuandong 《Journal of Solid State Electrochemistry》2022,26(2):491-501
Journal of Solid State Electrochemistry - Grapefruit peel carbon (GPC) is prepared from waste grapefruit peel and further used as substrate for in situ construction of MoS2 arrays, forming MoS2/GPC... 相似文献